Find all needed information about Metal Support Boundary Sites In Catalysis. Below you can see links where you can find everything you want to know about Metal Support Boundary Sites In Catalysis.
https://www.sciencedirect.com/science/article/pii/S0926860X97002433
The number of metal-support boundary sites in relation to total metal surface sites increases with increasing metal dispersion and, consequently, some of the phase-boundary sensitive reactions as the MCP hydrogenolysis on platinum exhibit a particle size effect.Cited by: 219
https://hungary.pure.elsevier.com/en/publications/metal-support-boundary-sites-in-catalysis
In highly-dispersed metal catalysts, the supporting oxide stabilises the metal particles, but may also promote individual reaction steps. In particular, many reactions are believed to proceed, preferentially or exclusively, at the metal-oxide interface which contains sites with distances between metal atoms and support in the range of atomic dimensions.Cited by: 219
https://www.sciencedirect.com/science/article/pii/S1876107017300524
Tuning/exploiting Strong Metal-Support Interaction (SMSI) in Heterogeneous Catalysis. ... The reaction takes place at the perimeter of the metal and the support and therefore the boundary population is the key property determining the reactivity of systems having dual reaction sites. Furthermore, the spillover of reactive species either on the ...Cited by: 74
http://pubs.acs.org/doi/abs/10.1021/acscatal.7b00979
The emergence of supercell density functional theory (DFT) over the past few decades has enabled great progress in rational catalyst design for extended surfaces of transition metals. However, insights from such metal-only models may not translate directly to metal nanoparticles dispersed on high surface area supporting phases, where metal and support may both participate in catalysis.Cited by: 12
https://pubs.acs.org/doi/pdf/10.1021/acscatal.6b00829
support can interact with the active phase through geometrical effects (e.g., strain due to presence of support), electronic effects (e.g., charge transfer between the metal and the oxide support),5a,6 or the creation of special interfacial sites (where sites at the metal−support interface are responsible for high
https://www.researchgate.net/publication/314468706_Tuningexploiting_Strong_Metal-Support_Interaction_SMSI_in_Heterogeneous_Catalysis
The strong metal-support interaction induces an electronic effect [5,36] which has been known in catalysis for over 50 years, since the work of Schwab [2,37] and Solymosi [38] .
https://www.researchgate.net/publication/271930263_Decoupling_the_electronic_geometric_and_interfacial_contributions_to_support_effects_in_heterogeneous_catalysis
Decoupling the electronic, geometric and interfacial contributions to support effects in heterogeneous catalysis ... of perimeter sites at the metal–oxide boundary. We target Fischer–Tropsch ...
https://www.deepdyve.com/lp/elsevier/catalysis-at-the-metal-support-interface-exemplified-by-the-2Zb0wb1uwk
Jul 25, 2003 · Read "Catalysis at the metal-support interface: exemplified by the photocatalytic reforming of methanol on Pd/TiO 2, Journal of Catalysis" on DeepDyve, the largest online rental service for scholarly research with thousands of academic publications available at your fingertips.
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5031120/
Sep 02, 2016 · Role of the Three-Phase Boundary of the Platinum–Support Interface in Catalysis: A Model Catalyst Kinetic Study ... (length of three-phase boundary between the Pt, support, ... , 5a,6 or the creation of special interfacial sites (where sites at the metal–support interface …Cited by: 4
https://www.nature.com/articles/s41563-018-0080-y
May 14, 2018 · Electron microscopy and modelling are used to study CO oxidation on oxide-supported Pd. The perimeter of the metal/oxide interface is shown to affect CO tolerance of the entire particle ...Cited by: 21
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